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New chalcogenide glasses in the GeSe2-Ga2Se3-In2Se3 and GeSe2-Ga2Se3-PbSe domains

Identifieur interne : 000844 ( Main/Repository ); précédent : 000843; suivant : 000845

New chalcogenide glasses in the GeSe2-Ga2Se3-In2Se3 and GeSe2-Ga2Se3-PbSe domains

Auteurs : RBID : Pascal:13-0344271

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English descriptors

Abstract

Two new chalcogenide glassy domains were explored by substituting Ga for In or Pb in compositions from the GeSe2-Ga2Se3 tie line in the Ge-Ga-Se ternary diagram. The thermal, optical and mechanical properties of these glasses were determined and the effect of the substitutions on these properties was assessed. It is shown that addition of lead tends to destabilize the glasses while the addition of indium tends to stabilize them. Both elements induce a systematic increase in the onset of transmission values and in the densities when substituted to gallium. The glasses synthesized represent good potential candidates for the production of glass-ceramics with photovoltaic or nonlinear properties.

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Pascal:13-0344271

Le document en format XML

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<title xml:lang="en" level="a">New chalcogenide glasses in the GeSe
<sub>2</sub>
-Ga
<sub>2</sub>
Se
<sub>3</sub>
-In
<sub>2</sub>
Se
<sub>3</sub>
and GeSe
<sub>2</sub>
-Ga
<sub>2</sub>
Se
<sub>3</sub>
-PbSe domains</title>
<author>
<name sortKey="Hubert, Mathieu" uniqKey="Hubert M">Mathieu Hubert</name>
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<s1>Equipe Verres et Céramiques, UMR 6226 Institut des Sciences Chimiques de Rennes, Campus de Beaulieu, Avenue du Général Leclerc</s1>
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<author>
<name sortKey="Calvez, Laurent" uniqKey="Calvez L">Laurent Calvez</name>
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<s1>Equipe Verres et Céramiques, UMR 6226 Institut des Sciences Chimiques de Rennes, Campus de Beaulieu, Avenue du Général Leclerc</s1>
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<author>
<name sortKey="Zhang, Xiang Hua" uniqKey="Zhang X">Xiang-Hua Zhang</name>
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<idno type="ISSN">0022-3093</idno>
<title level="j" type="abbreviated">J. non-cryst. solids</title>
<title level="j" type="main">Journal of non-crystalline solids</title>
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<term>Gallium</term>
<term>Glass</term>
<term>Indium additions</term>
<term>Lead additions</term>
<term>Mechanical properties</term>
<term>Non linear effect</term>
<term>Optical properties</term>
<term>Photovoltaic cell</term>
<term>Photovoltaic effects</term>
<term>Thermal properties</term>
<term>Vitreous state</term>
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<term>Etat vitreux</term>
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<term>Effet photovoltaïque</term>
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<term>Verre</term>
<term>Ga2Se3</term>
<term>In2Se3</term>
<term>PbSeS</term>
<term>8105K</term>
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<div type="abstract" xml:lang="en">Two new chalcogenide glassy domains were explored by substituting Ga for In or Pb in compositions from the GeSe
<sub>2</sub>
-Ga
<sub>2</sub>
Se
<sub>3</sub>
tie line in the Ge-Ga-Se ternary diagram. The thermal, optical and mechanical properties of these glasses were determined and the effect of the substitutions on these properties was assessed. It is shown that addition of lead tends to destabilize the glasses while the addition of indium tends to stabilize them. Both elements induce a systematic increase in the onset of transmission values and in the densities when substituted to gallium. The glasses synthesized represent good potential candidates for the production of glass-ceramics with photovoltaic or nonlinear properties.</div>
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<s1>ISNOG 2012 Proceedinfs of the 18
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<s0>Two new chalcogenide glassy domains were explored by substituting Ga for In or Pb in compositions from the GeSe
<sub>2</sub>
-Ga
<sub>2</sub>
Se
<sub>3</sub>
tie line in the Ge-Ga-Se ternary diagram. The thermal, optical and mechanical properties of these glasses were determined and the effect of the substitutions on these properties was assessed. It is shown that addition of lead tends to destabilize the glasses while the addition of indium tends to stabilize them. Both elements induce a systematic increase in the onset of transmission values and in the densities when substituted to gallium. The glasses synthesized represent good potential candidates for the production of glass-ceramics with photovoltaic or nonlinear properties.</s0>
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